Photooxygenation of alkynylperylenes. Formation of dibenzo[jk,mn]phenanthrene-4,5-diones |
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Authors: | Maeda Hajime Nanai Yasuaki Mizuno Kazuhiko Chiba Junya Takeshima Sakiko Inouye Masahiko |
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Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka, Japan. maeda-h@chem.osakafu-u.ac.jp |
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Abstract: | 3-(1-Alkynyl)perylenes undergo oxygenation when subjected to irradiation with visible light under aerated conditions. The structures of novel oxygenated products formed in this manner are assigned as regioisomeric dibenzo[jk,mn]phenanthrene-4,5-diones. |
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