Porphyrins. 40. Chemistry of Oximes of Metal Complexes of meso-Formyloctaalkylporphyrins. Synthesis,Molecular and Crystal Structure of Nickel Complexes of “Tripyrrolylisoxazoles” |
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| Authors: | Yu. V. Morozova V. V. Nesterov D. V. Yashunsky M. Yu. Antipin G. V. Ponomarev |
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| Affiliation: | (1) Institute of Biomedical Chemistry, Russian Academy of Medical Sciences, Moscow, 119121, Russia;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813, Russia |
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| Abstract: | The synthesis has been carried out of nickel complexes of oximes of two isomers of meso-formyletioporphyrin-II and their conversion in the heterophase system methylene chloride-water into nickel complexes of tripyrrolylisoxazoles has been studied. The structure of one of them was established by X-ray structural analysis.__________Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 697–704, May, 2005. |
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| Keywords: | isoxazole linear polypyrroles porphyrin metal complexes oximes of meso-formylporphyrins etioporphyrin-II |
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