Effect of crown ethers on the solvent extraction and separation of lanthanide(III) ions with 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one |
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Authors: | Maria A. Petrova Ivan L. Dukov |
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Affiliation: | (1) Department of Inorganic Chemistry, University of Chemical Technology and Metallurgy, 8 Kl. Okhridski, 1756 Sofia, Bulgaria |
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Abstract: | Synergistic solvent extraction of 14 lanthanides with mixtures of 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one (HP) and the crown ethers (S), 18-crown-6, benzo-18-crown-6 or dibenzo-18-crown-6 from an aqueous chloride medium with the constant ionic strength of 0.1 mol dm−3 was investigated using benzene as a diluent. The composition of the species extracted was determined as LnP3 · S. The addition of a crown ether to the chelating extractant produced rather significant synergistic effects. On basis of experimental data, values of equilibrium constants, synergistic coefficients, and separation factors were calculated. |
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Keywords: | synergistic extraction lanthanides 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one 18-crown-6 benzo-18-crown-6 dibenzo-18-crown-6 ethers |
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