| Zinc Borohydride-Ionic Liquid： Stable and Efficient System for Reductive Reaction of Aldehydes with Primary Amines to Corresponding Secondary Amines |
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| 作者姓名： | NIAN Bao-yi XU Gang WU Jiang-ping YANG Li-rong |
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| 作者单位： | [1]Department of Chemistry and Biology Engineering, Sanming University, Sanming 365004, P. R. China [2]College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, P. R. China |
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| 基金项目： | 国家自然科学基金，国家重点基础研究发展计划(973计划) |
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| 摘 要： | Ionic liquids（ILs） are attracting much attention in various fields of chemical synthesis, electrochemical applications, liquid-liquid extractions, as well as biotransformations. Among those fields, the application of ILs as the potential green solvent for a wide variety of synthetic processes is an area of intense researches. High yield, high selectivity, and good catalytic charac-teristics have usually been achieved. After the isolation of products, ILs can usually be recovered and recycled many times by simple treating procedures, such as, filtration, extraction, and dryness.
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| 关 键 词： | 锌 化合物 稳定性 还原剂 胺 |
| 收稿时间： | 2007-03-19 |
| 修稿时间： | 2007-04-10 |
Zinc Borohydride-Ionic Liquid: Stable and Efficient System for Reductive Reaction of Aldehydes with Primary Amines to Corresponding Secondary Amines |
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| NIAN Bao-yi XU Gang WU Jiang-ping YANG Li-rong.Zinc Borohydride-Ionic Liquid: Stable and Efficient System for Reductive Reaction of Aldehydes with Primary Amines to Corresponding Secondary Amines[J].Chemical Research in Chinese University,2008,24(1):120-122. |
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| Authors: | Bao-yi NIAN Gang XU Jiang-ping WU Li-rong YANG |
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| Institution: | aDepartment of Chemistry and Biology Engineering, Sanming University, Sanming 365004, P. R. China;bCollege of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, P. R. China |
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| Abstract: | 1 Introduction Ionic liquids(ILs) are attracting much attention in various fields of chemical synthesis, electrochemical applications, liquid-liquid extractions, as well as biotransformations. Among those fields, the application of ILs as the potential green solvent for a wide variety of synthetic processes is an area of intense researches.High yield, high selectivity, and good catalytic charac-teristics have usually been achieved. After the isolation of products, ILs can usually be recovered and recycled many times by simple treating procedures,such as, filtration, extraction, and dryness. Because of their superiorities mentioned earlier, together with their unique physicochemical characters of negligible vapor pressure, thermal stability, and favorable solubility of various chemicals, ILs have received extensive attention by organic researchers recently1]. |
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| Keywords: | Ionic liquid Zinc borohydride Reductive amination BMImBF4 |
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