| Asymmetric total syntheses of (+)-goniopypyrone and (+)-9-deoxygoniopypyrone |
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| 引用本文： | YANG,Zhi-Cai ZHOU,Wei-ShanShanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China. Asymmetric total syntheses of (+)-goniopypyrone and (+)-9-deoxygoniopypyrone[J]. 中国化学, 1996, 14(2): 152-159. DOI: 10.1002/cjoc.19960140210 |
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| 作者姓名： | YANG Zhi-Cai ZHOU Wei-ShanShanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 China |
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| 作者单位： | YANG，Zhi-Cai ZHOU，Wei-ShanShanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China. |
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| 摘 要： | Asymmetric total syntheses of (+)-goniopypyrone (1) and (+)-deoxygoniopypyrone (2) from methyl cinnamate (7) via (DHQ)2-PHAL-OsO4 catalyzed asymmetric dihydroxylation and highly stereoselective 2-furylcopper addition in eight steps and eleven steps with overall yield of 20% and 13%,respectively,are described.
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Asymmetric total syntheses of (+)-goniopypyrone and (+)-9-deoxygoniopypyrone |
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| YANG,Zhi-Cai ZHOU,Wei-Shan. Asymmetric total syntheses of (+)-goniopypyrone and (+)-9-deoxygoniopypyrone[J]. Chinese Journal of Chemistry, 1996, 14(2): 152-159. DOI: 10.1002/cjoc.19960140210 |
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| Authors: | YANG Zhi-Cai ZHOU Wei-Shan |
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| Affiliation: | YANG,Zhi-Cai ZHOU,Wei-ShanShanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China |
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| Abstract: | Asymmetric total syntheses of (+)-goniopypyrone (1) and (+)-deoxygoniopypyrone (2) from methyl cinnamate (7) via (DHQ)2-PHAL-OsO4 catalyzed asymmetric dihydroxylation and highly stereoselective 2-furylcopper addition in eight steps and eleven steps with overall yield of 20% and 13%,respectively,are described. |
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| Keywords: | Asymmetric total synthesis goniopypyrone 9-deoxygoniopypyrone 2-furylcopper |
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