| [Co(amp)2Cl2]2[ZnCl4]体系中两对称异构体的2D NMR研究 |
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| 引用本文： | 张建新,郭辉瑞,陶朱,祝黔江,罗绪强.[Co(amp)2Cl2]2[ZnCl4]体系中两对称异构体的2D NMR研究[J].无机化学学报,2002,18(9):915-920. |
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| 作者姓名： | 张建新 郭辉瑞 陶朱 祝黔江 罗绪强 |
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| 作者单位： | 1. 贵州省天然产物重点化学实验室
2. 贵州大学应用化学研究所,贵阳,550025 |
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| 基金项目： | 贵州省重点实验室基金项目，贵州省省长基金。 |
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| 摘 要： | The two symmetrical isomers in Co(amp)2Cl2]2ZnCl4](amp=2-(Aminomethyl)pyridine) system were syn-thesized by general oxidation method and were separated by chromatography and recrystallization method. Their configurations were assigned by using 2D NMR techniques, particularly the NOESY NMR spectra. Solvent used was Me2SO-d6 with the central peak of the CD3 septet as the reference ( 13C,δ 39.37; 1H,δ 2.49 relative to SiMe4). Cation exchange media used was Dowex 50Wx 2(H+ form, 200～400mesh; Biorad).
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| 关 键 词： | 钴(Ⅲ)配合物 对称异构体 二维核磁共振谱 |
| 修稿时间： | 2002年3月6日 |
Study on 2D NMR Spectra of Two Symmetrical Isomers in [Co(amp)2Cl2]2[ZnCl4] System |
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| ZHANG Jian-Xin,GUO Hui-Ru,TAO Zhu,ZHU Qian-Jiang and LUO Xu-Qiang.Study on 2D NMR Spectra of Two Symmetrical Isomers in [Co(amp)2Cl2]2[ZnCl4] System[J].Chinese Journal of Inorganic Chemistry,2002,18(9):915-920. |
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| Authors: | ZHANG Jian-Xin GUO Hui-Ru TAO Zhu ZHU Qian-Jiang and LUO Xu-Qiang |
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| Institution: | Key Laboratory of Chemistry for Natural Products of Guizhou Province, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025 and Institute of Applied Chemistry, Guizhou University, Guiyang 550025 |
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| Abstract: | |
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| Keywords: | Co? complexes symmetrical isomer 2D NMR spectra |
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