Trace Element Determination in Diesel Particulates by Total-Reflection X-Ray Fluorescence Analysis |
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| Authors: | Juha K Vilhunen Alex von Bohlen Martina Schmeling Leena Rantanen Seppo Mikkonen Reinhold Klockenkämper Dieter Klockow |
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| Institution: | (1) Neste Oy, Corporate Technology, P. O. Box 310, FIN-06101 Porvoo, Finland, FI;(2) Institut für Spektrochemie und Angewandte Spektroskopie – ISAS, P. O. Box 101352, D-44013 Dortmund, Germany, DE;(3) Neste Oy, Oil Research, P. O. Box 310, FIN-06101 Porvoo, Finland, FI |
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| Abstract: | Particulate matter of Diesel emissions collected from diluted exhaust during standard test runs with two Diesel fuels of
different sulfur content was analysed by total-reflection X-ray fluorescence (TXRF). The trace elements determined were S,
Ca, Cr, Mn, Fe, Ni, Cu, Zn and Pb. Additionally, some filter materials were tested with respect to their applicability for
sample collection. Quartz fibre filters were found to be most suitable, both from a technical and a chemical point of view.
A clear reduction of total particulate emissions during the whole test was observed when the fuel with very low sulfur content
was used. In addition, it was found that the wear metal content of particulate matter emitted by a cold engine was higher
than that observed during normal engine working temperature.
Received September 10, 1998. Revision March 2, 1999 |
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| Keywords: | , ,total-reflection X-ray fluorescence, trace element analyses, Diesel fuel, Diesel particulates, |
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