| 水杨醛缩胺类Schiff碱光致变色性质 |
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| 引用本文： | 赵建章,赵冰,徐蔚青,刘举正. 水杨醛缩胺类Schiff碱光致变色性质[J]. 高等学校化学学报, 2003, 24(2): 324-328 |
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| 作者姓名： | 赵建章 赵冰 徐蔚青 刘举正 |
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| 作者单位： | 1. 教育部超分子结构与谱学重点实验室, 吉林大学, 长春 130023;2. 吉林大学化学学院, 长春 130023;3. 东南大学化学化工系, 南京 210096 |
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| 基金项目： | 国家自然科学基金 (批准号 :2 9975 0 11,2 0 1730 19)资助 |
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| 摘 要： | 用时间相关光谱法研究了水杨醛缩胺类Schiff碱光致变色的性质,发现分子共轭体系大小和分子骨架刚性等因素对光致变色性质存在规律性的影响.共轭体系越大,发生光致变色的速率越小;分子骨架的刚性越大,化合物越难发生光致变色;反之,则光致变色较容易进行.
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| 关 键 词： | 水杨醛缩胺类Schiff碱 光致变色 时间相关光谱法 荧光光谱 紫外-可见光谱 |
| 文章编号： | 0251-0790(2003)02-0324-05 |
| 收稿时间： | 2001-09-07 |
Spectroscopy Study on Photochromism of Salicylaldehyde-derived Schiff Bases |
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| ZHAO Jian-Zhang ,,ZHAO Bing ,XU Wei-Qing ,LIU Ju-Zheng. Spectroscopy Study on Photochromism of Salicylaldehyde-derived Schiff Bases[J]. Chemical Research In Chinese Universities, 2003, 24(2): 324-328 |
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| Authors: | ZHAO Jian-Zhang ZHAO Bing XU Wei-Qing LIU Ju-Zheng |
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| Affiliation: | 1. The Key Laboratory of Supramolecular Structure and Spectroscopy of Ministry of Education, Jilin University, Changchun 130023, China;2. College of Chemistry, Jilin University, Changchun 130023, China;3. Department of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, China |
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| Abstract: | The photochromism of salicylaldehyde-derived Schiff bases were studied from a view-point of structure-property relationship. It was found that the π-conjugated system and the flexibility of the molecular skeleton play an important role in the determination of the photochromic behavior. The molecules with smaller π-conjugated systems or flexible skeletons are easy to undergo the photochromism. |
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| Keywords: | Salicylaldehyde-derived Schiff base Photochromism Time-dependent spectroscopy Fluorescence spectroscopy UV-Vis spectroscopy |
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