Electron spin echo envelope modulation from trapped electrons in a glassy medium |
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| Authors: | MK Bowman Larry Kevan IM Brown |
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| Institution: | Department of Chemistry, Wayne State University, Detroit, Michigan 48202, USA;McDonnell Douglas Research Laboratories, McDonnell Douglas Corporation, St. Louis, Missouri 63166, USA |
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| Abstract: | An amplitude modulation of the electron spin echo envelope has been observed for radiation-produced trapped electrons in 10 M NaOD/D2O at 77°K but not in 10 M N2OH/H2O. The modulation has been simulated theoretically by generalizing the single crystal model of Rowan et al. to disordered systems. The modulation has been interpreted as due to dipolar interactions with deuterons in molecules of the second solvation shell around the trapped electrons. |
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