Mössbauer spectroscopy of 57Fe in NH4MnCl3, NH4FeCl3 and NH4CoCl3 |
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Authors: | L Asch JM Friedt C Lupiani J Tornero |
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Institution: | Laboratoire de Chimie Nucléaire, Centre de Recherches Nucléaires et Université Louis Pasteur, 67037 Strasbourg Cédex, France |
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Abstract: | The Mössbauer spectra of 57Fe doped NH4MnCl3 reveal that this compound undergoes a crystallographic phase transition at 258°K and becomes magnetic at 105°K. No crystallographic transition appeared either in NH4FeCl3 or in 57Fe:NH4CoCl3; the latter orders magnetically around 27°K. |
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