Sulphur Kβ X-ray emission spectra of SO2−3 and SO3F− ions |
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| Authors: | Seppo Aksela Matti Karras |
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| Affiliation: | Department of Technical Physics, University of Oulu, Oulu, Finland;Department of Electrical Engineering, University of Oulu, Oulu, Finland |
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| Abstract: | The SKβ X-ray emission spectra of the SO2?3 and SO3F? ions are studied in detail and the observed fine structures are interpreted with the aid of existing molecular orbital (MO) calculations. The different MO methods are compared with regard to success and the effect of d-orbitals is discussed. The spectrometer is a double-crystal type with an instrument fwhm resolution of 0.25 eV for SKβ X-rays. |
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