The fluorescence lifetimes of the methyl-substituted benzyl,triphenylmethyl and diphenylmethyl radicals

Time resolved fluorescence of some methyl-substituted benzyl, triphenylmethyl, and diphenylmethyl radicals trapped in rigid solvents at low temperature has been observed. These radicals were excited by pulsed N₂ laser at 337 nm. It is found that these radicals exhibit very long fluorescence lifetime. The long lifetimes of these radicals seem to indicate that the first doublet-doublet electronic transitions of the radicals have a forbidden character.