Vibrational energy exchange of the DF (ν=2) state with DF (ν=0) |
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Authors: | Jerry F Bott |
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Institution: | The Aerospace Corportion, El Segundo, California, USA |
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Abstract: | The energy transfer rate for the reaction DF (ν=1) + DF (ν=1)kνν→ DF (ν=0) + DF (ν=2) + ΔE=91.6 cm?1 has been studied in a combined shock-tube laser-induced fluorescence experiment at temperatures from 295 to 720°K. The rate coefficient kνν for the exothermic reaction was found to vary as T?1 when expressed in units of cm3/mole sec. At T=295°K, the probability of the reaction is approximately 0.2 per collision. |
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