The magnetically induced circular emission spectrum of Cr(III) in guanidinium aluminium sulphate |
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| Authors: | A.J. McCaffery P. Brint R. Gale R.A. Shatwell |
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| Affiliation: | School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ, UK |
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| Abstract: | The magnetically induced, circular emission spectrum (MICE) of Cr(III) in hexagonal guanidinium aluminium sulphate hexahydrate has been measured together with the axial emission spectrum. Four lines are observed in the 2E region suggesting that these are the result of trigonal field and site symmetry splittings since each component exhibits an A term type dispersion. The MICE spectrum enables several of the vibrational features to be identified. |
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