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A method for obtaining potential parameters for helium from T1 measurements
Authors:B Shizgal
Institution:Department of Chemistry, The University of British Columbia, Vancouver 8, British Columbia, Canada
Abstract:The temperature dependence of T1 for 3He gas in the range 0–4°K is calculated for a Lennard-Jones (12,6) potential. The relaxation of the nuclear spins is assumed to be due to a dipolar interaction between the nuclei. A minimum value in the relaxation time, T1,min, is found to occur at a temperature denoted by Tmin. By repeating the calculation for different pairs of values of the potential parameters ? and σ, we have found that for a density of 10?2 g/cm32Tmin = 13.0?1.12 × 1032, T1,min2(Tmin)12 = 17.4?6.56 × 1022, with ?, σ, Tmin and T1,min in eV, Å, °K and minutes, respectively. From measurements of Tmin and T1,min, ? and σ can be determined.
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