Comments on the indo calculation of hyperfine coupling in the σ phenyl radical |
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| Authors: | Rowland J. Hayward Bryan R. Henry |
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| Affiliation: | Department of Chemistry, University of Manitoba, Winnipeg, Canada R3T 2N2 |
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| Abstract: | The relative magnitudes and signs of the hyperfine coupling constants in the phenyl radical, calculated by INDO, are explained by a combination of delocalization of electron spin density into the sigma framwork and a modification of the exchange polarization effects commonly observed for π-type radicals. |
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