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在La-TiO2催化剂上由苯酚直接氧化制取邻苯二酚的研究
引用本文:邓国才.在La-TiO2催化剂上由苯酚直接氧化制取邻苯二酚的研究[J].中国稀土学报,1999,17(2):116-119.
作者姓名:邓国才
作者单位:南开大学化学系
摘    要:以La-TiO2作为苯酚选择氧化催化剂,用过氧化氢氧化,得到邻苯二酚选择性高达90%的良好结果,讨论了溶剂,反应温度,反应时间,过氧化氢浓度,催化剂用量,过氧化氢用量等工艺条件对苯酚羟基化作用的影响。

关 键 词:稀土  邻苯二酚    钛胶  催化剂  苯酚  羟基化

Phenol Hydroxylation Reaction on LanthanumTitania Catalyst for Catechol
Deng Guocai,Li Qinggang,Chen Rongti.Phenol Hydroxylation Reaction on LanthanumTitania Catalyst for Catechol[J].Journal of the Chinese Rare Earth Society,1999,17(2):116-119.
Authors:Deng Guocai  Li Qinggang  Chen Rongti
Abstract:The selective H2O2 oxidation reaction of phenol on LaTiO2 catalyst for catechol was investigated and the selectivity was increased by 90% comparing with that of bare titania catalyst. The effects of solvent, reaction temperature and time, concentration of hydrogen peroxide and ratio of feed upon reaction were discussed.
Keywords:Rare earths  Catechol  Lanthanumtitania    catalyst  Phenol hydroxylation
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