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Thermal rearrangement of phosphine-B(C6F5)3 adducts |
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| Authors: | Welch Gregory C Holtrichter-Roessmann Thorsten Stephan Douglas W |
| Institution: | Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada N9B 3P4. |
| Abstract: | A series of tertiary and secondary phosphine-B(C6F5)3 adducts are shown to undergo facile, thermal-induced rearrangement to give zwitterionic species of the form R3P(C6F4)BF(C6F5)2 and R2PH(C6F4)BF(C6F 5)2, respectively. |
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