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高吸水性树脂
引用本文:邱海霞,于九皋,林通. 高吸水性树脂[J]. 化学通报, 2003, 66(9): 598-605
作者姓名:邱海霞  于九皋  林通
作者单位:天津大学理学院,天津360072
基金项目:高等学校博士点资助项目 (2 0 0 2 0 0 5 5 6 0 18)
摘    要:用热力学理论和相转变理论阐明了高吸水性树脂的吸水机理。解释了高分子链上的电荷密度、外界溶液离子强度以及交联度对吸水倍数的影响,并指出了影响吸水速率的因素。介绍了淀粉类、纤维素类、共聚合类、复合类以及可生物降解类高吸水性树脂近30年来的研究状况以及存在的问题,简要介绍了高吸水性树脂的应用。

关 键 词:高吸水性树脂 超强吸水剂 高分子材料 热力学 合成
修稿时间:2002-09-25

Superabsorbent Polymer
Qiu Haixia,Yu Jiugao ,Lin Tong. Superabsorbent Polymer[J]. Chemistry, 2003, 66(9): 598-605
Authors:Qiu Haixia  Yu Jiugao   Lin Tong
Affiliation:Qiu Haixia,Yu Jiugao *,Lin Tong
Abstract:The mechanism of high water absorbency of superabsorbent polymers was explained according to thermaldynamic theory and phase transition theory.Water absorbency was interpreted in terms of the presence of ionic groups on the backbone, ionic strength in external solution,as well as crosslinking density. Factors that affect water absorbent rate were presented. The development of super water absorbents based on starch, cellulose,copolymer, composite and biodegradable polymer during the last thirty years was describled.The tendency of the research of superabsorbent polymer was predicited and the application of super water absorbents was briefly introduced.
Keywords:High water absorbent polymer   Superabsorbent
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