Octaline and decalone derivatives from a new annulation reaction in enamine field |
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Authors: | G Pitacco A Risaliti ML Trevisan E Valentin |
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Institution: | Istituto di Chimica, Universitá, 34127 Trieste, Italy |
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Abstract: | An octaline system is obtained from the reaction between 2-cyclohexenyl-1-morpholino-ethene and β-nitrostyrene, carried out under kinetic control. By hydrolysis, it is converted to a 1-decalone derivative, which is also a kinetic control product. The stereochemical aspects of formation and equilibration of the products are examined. |
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