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Indoor atmospheric corrosion of conventional weathering steels in the tropical atmosphere of Panama
Authors:Juan A Jaén  Josefina Iglesias  Olga Adames
Institution:1. Depto. de Química Física, CITEN, Edificio de Laboratorios Científicos-VIP, Universidad de Panamá, Panamá, Panamá
2. Laboratorio de Química y Física Aplicada, Universidad Tecnológica de Panamá, Panamá, Panamá
3. Escuela de Química, Universidad de Panamá, Panamá, Panamá
Abstract:One year indoor atmospheric corrosion examinations have been carried out on two conventional weathering steels for a year, at two test sites, Tocumen and Sherman Breakwater in Panama. They are environmentally classified by ISO 9223 as S1P0 τ 4 and S3P0 τ 5, respectively. In this humid-tropical marine climate corrosion rates are rather high, especially at Sherman Breakwater test site, mainly due to the high deposition of chloride, among other environmental conditions. Our results indicate that indoor corrosion is highly determined by the time of wetness and chloride ions. A-588 weathering steel corroded at a generally lower rate than COR-420 weathering steel. Rust characterization was performed by XRD, FTIR, and Mössbauer spectroscopy. Lepidocrocite, goethite, maghemite and akaganeite were found as corrosion products. Akaganeite is only detected when high chlorides deposition rates are obtained, and no washing effect occurs. This phase, together with maghemite, is obtained when there is greater aggressiveness in the environment.
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