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Hydrogen bond lengths in aqueous hydroxylammonium nitrate as a function of concentration,temperature and pressure
Authors:Robert A. Fifer
Affiliation:(1) US Army Ballistic Research Laboratory, 21005 Aberdeen Proving Ground, MD, USA
Abstract:Qualitative and quantitative information about the interspecies distance distributions in aqueous hydroxylammonium nitrate (HAN) is obtained as a function of concentration (7 to 17M), temperature (–120 to 60°C) and pressure (0.1 to 7100 MPa) using isotopic uncoupling techniques for the O-HctdotO and N-HctdotO hydrogen bonds in conjunction with frequency-distance correlations.
Keywords:hydroxylammonium nitrate  FTIR  hydrogen bonding  intermolecular distances
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