| 合成光学活性菊酸酯的方法 |
| |
| 引用本文： | 李争宁,陈惠麟.合成光学活性菊酸酯的方法[J].合成化学,2000,8(6):469-471. |
| |
| 作者姓名： | 李争宁 陈惠麟 |
| |
| 作者单位： | 中国科学院大连化学物理研究所,大连,116023 |
| |
| 摘 要： | Ｌ－孟醇与过量外消旋菊酰氯反应表现出非对映异构体选择性，得到了光学活性菊酸的Ｌ－孟醇酯。由外消旋菊酸的Ｌ－孟醇酯经异构化反应也得到了光学活性菊酸的Ｌ－孟醇酯。
|
| 关 键 词： | 菊酸酯 合成 光学活性 手性识别 L－孟醇酯 |
Novel Synthesis of Optically Active Chrysanthemic Acid Ester |
| |
| Abstract.Novel Synthesis of Optically Active Chrysanthemic Acid Ester[J].Chinese Journal of Synthetic Chemistry,2000,8(6):469-471. |
| |
| Authors: | Abstract |
| |
| Abstract: | L-Menthanol ester of chiral chrysanthemic acid was obtained via stereoselective esterification of the racemic acid, and the result was analyzed by MOPAC. Promoted by the above phenomenon, we obtained L-menthol ester of chiral chrysanthemic acid via the isomerization of L-menthol ester of racemic chrysanthemic acid. |
| |
| Keywords: | Menthanol Isomerization Chrysanthemic acid Steroselectivity Esterification |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
