Electrochemical behaviour of tetravalent thorium in molten /Li-K/Cl eutectic |
| |
| Authors: | L. Martinot |
| |
| Affiliation: | (1) Laboratory of Analytical Chemistry and Radiochemistry, B6, University of Liège, Sart Tilman, B-4000 Liège, Belgium;(2) Present address: Research Associate of the Inter-University Institute for Nuclear Sciences, Brussels |
| |
| Abstract: | The electrochemical reduction of Th/IV/ in the /Li–K/Cl eutectic between 400 and 500 °C proceeds according to a four electron process without any intermediate step. The reduction is quasi-reversible and the diffusion coefficient deduced from the peak current of the voltammetric reduction equals 2.7×10–6 cm2 sec–1 at 400°C. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
