Catalytic behaviour of Mo-based catalysts in liquid phase epoxidation of propylene by hydroperoxides |
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| Authors: | P Forzatii and F Trifirò |
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| Institution: | (1) Instituto di Chimica Industriale del Politecnico di Milano, Italy |
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| Abstract: | The activity of different Mo-based catalysts in propylene epoxidation by t-BuO2H was investigated. MoO2(C13H10O2N)2 and MoO2 (oxine)2 gave quantitative yields in propylene oxide; other compounds were inactive and MoO2 (acac)2 was less active and selective.The different catalytic behaviour of these catalysts is attributed to the different strength of Mo-ligand bonds.
                        t-BuO2H. MoO2 (C13H10O2N)2 MoO2 ()2  ;    , MoO2 (acac)2 . Mo-.
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