| Mn3O4多面体纳米晶体的制备及其电化学性能 |
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| 引用本文： | 杨陆峰,高 闯,郑明涛,胡超凡,崔江虎,刘应亮.Mn3O4多面体纳米晶体的制备及其电化学性能[J].无机化学学报,2013,29(2):381-388. |
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| 作者姓名： | 杨陆峰 高 闯 郑明涛 胡超凡 崔江虎 刘应亮 |
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| 作者单位： | 1. 暨南大学化学系纳米化学研究所,广州,510632
2. 华南农业大学理学院,广州,510642 |
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| 基金项目： | 国家自然科学基金(No.21031001,No.20906037);广东省高等学校科技创新重点项目(No.cxzd1014)资助项目 |
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| 摘 要： | 通过对未加添加剂的醋酸锰-乙醇体系的一种简易的水基热解过程,制备了Mn3O4多面体纳米晶体。借助X射线衍射仪(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、傅里叶变换红外光谱法(FTIR)、拉曼光谱和X-射线光电子能谱(XPS)等对Mn3O4的结构和形貌进行了表征。提出了Mn3O4多面体纳米晶体的形成机理。循环伏安法(CV)测试结果表明,所制得的Mn3O4电极呈现良好的赝电容性能。在扫描速率为5 mV.s-1时,得到了Mn3O4的最大比电容值173 F.g-1。
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| 关 键 词： | 纳米结构 氧化物 水热法 电化学性能 |
Synthesis and Electrochemical Properties of Mn3O4 Polyhedral Nanocrystals |
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| YANG Lu-Feng,GAO Chuang,ZHENG Ming-Tao,HU Chao-Fan,CUI Jiang-Hu and LIU Ying-Liang.Synthesis and Electrochemical Properties of Mn3O4 Polyhedral Nanocrystals[J].Chinese Journal of Inorganic Chemistry,2013,29(2):381-388. |
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| Authors: | YANG Lu-Feng GAO Chuang ZHENG Ming-Tao HU Chao-Fan CUI Jiang-Hu and LIU Ying-Liang |
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| Institution: | Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632, China;Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632, China;College of Science, South China Agricultural University, Guangzhou 510642, China;Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632, China;Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632, China;College of Science, South China Agricultural University, Guangzhou 510642, China |
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| Abstract: | Hausmannite Mn3O4 polyhedral nanocrystals have been fabricated through a simple solution-based thermolysis process in the manganese acetate-alcohol system. Structural and morphological characterizations of the as-obtained product have been carried out using XRD, FTIR, Raman spectraoscopy, XPS, SEM and TEM. The formation mechanism of polyhedral nanocrystals was proposed. The cyclic voltammetry (CV) result show that the as prepared Mn3O4 electrode exhibits a good pseudo-capacitance behavior. A maximum specic capacitance of 173 F·g-1 is obtained for the nanocrystals at a sweep rate of 5 mV·s-1. |
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| Keywords: | nanostructures oxides hydrothermal electrochemical properties |
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