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Ferroelectric behaviour of 30nm BaTiO3 ceramics prepared by high pressure assisted sintering
引用本文:肖长江,迟振华,李凤英,冯少敏,靳常青,王晓慧,邓湘云,李龙土. Ferroelectric behaviour of 30nm BaTiO3 ceramics prepared by high pressure assisted sintering[J]. 中国物理, 2007, 16(10): 3125-3128
作者姓名:肖长江  迟振华  李凤英  冯少敏  靳常青  王晓慧  邓湘云  李龙土
作者单位:Institute of Physics, Chinese Academy ofScience, Beijing 100080, China;Institute of Physics, Chinese Academy ofScience, Beijing 100080, China;Institute of Physics, Chinese Academy ofScience, Beijing 100080, China;Institute of Physics, Chinese Academy ofScience, Beijing 100080, China;Institute of Physics, Chinese Academy ofScience, Beijing 100080, China;State Key Laboratory of New Ceramics and Fine Processing,Department of Materials Science and Engineering, TsinghuaUniversity, Beijing 100084, China;State Key Laboratory of New Ceramics and Fine Processing,Department of Materials Science and Engineering, TsinghuaUniversity, Beijing 100084, China;State Key Laboratory of New Ceramics and Fine Processing,Department of Materials Science and Engineering, TsinghuaUniversity, Beijing 100084, China
基金项目:Project supportedby the Ministry of Sciences and Technology of China through 973project (Grant No 2002B613301).
摘    要:Dense nanocrystalline BaTiO3 ceramics with a homogeneous grain size of 30 nm was obtained by pressure assisted sintering. The ferroelectric behaviour of the ceramics was characterized by the dielectric peak at around 120 ℃, the P-E hysteresis loop and some ferroelectric domains. These experimental results indicate that the critical grain size for the disappearance of ferroelectricity in nanocrystalline BaTiO3 ceramics fabricated by pressure assisted sintering is below 30 nm. The ferroelectric property decreasing with decreasing grain size can be explained by the lowered tetragonality and the 'dilution' effect of grain boundaries.

关 键 词:钛酸钡陶瓷 高压烧结 纳米晶陶瓷 铁电性质
收稿时间:2006-08-13
修稿时间:2006-08-13

Ferroelectric behaviour of 30nm BaTiO3 ceramics prepared by high pressure assisted sintering
Xiao Chang-Jiang,Chi Zhen-Hu,Li Feng-Ying,Feng Shao-Min,Jin Chang-Qing,Wang Xiao-Hui,Deng Xiang-Yun and Li Long-Tu. Ferroelectric behaviour of 30nm BaTiO3 ceramics prepared by high pressure assisted sintering[J]. Chinese Physics, 2007, 16(10): 3125-3128
Authors:Xiao Chang-Jiang  Chi Zhen-Hu  Li Feng-Ying  Feng Shao-Min  Jin Chang-Qing  Wang Xiao-Hui  Deng Xiang-Yun  Li Long-Tu
Affiliation:Institute of Physics, Chinese Academy of Science, Beijing 100080, China b
Abstract:Dense nanocrystalline BaTiO3 ceramics with a homogeneousgrain size of 30,nm was obtained by pressure assistedsintering. The ferroelectric behaviour of the ceramics wascharacterized by the dielectric peak at around 120,du, the$P$-$E$ hysteresis loop and some ferroelectric domains. Theseexperimental results indicate that the critical grain size forthe disappearance of ferroelectricity in nanocrystallineBaTiO3 ceramics fabricated by pressure assisted sinteringis below 30,nm. The ferroelectric property decreasing withdecreasing grain size can be explained by the loweredtetragonality and the `dilution' effect of grain boundaries.
Keywords:BaTiO3   pressure assistedsintering   nanocrystalline ceramics   ferroelectric behaviour
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