Comparative Catalytic Activity of Group 9 [Cp*MIII] Complexes: Cobalt‐Catalyzed CH Amidation of Arenes with Dioxazolones as Amidating Reagents |
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| Authors: | Juhyeon Park Prof?Dr Sukbok Chang |
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| Institution: | 1. Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305‐701 (Republic of Korea);2. Center for Catalytic Hydrocarbon Functionalization, Institute for Basic Science (IBS), Daejeon 305‐701 (Republic of Korea) |
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| Abstract: | A procedure for the Cp*CoIII]‐catalyzed direct C? H amidation of arenes with dioxazolone has been developed. This reaction proceeds under straightforward and mild conditions with a broad range of substrates, including anilides. A comparative study on the catalytic activity of Group 9 {Cp*MCl2}2] complexes revealed the unique efficiency of the cobalt catalyst. |
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| Keywords: | amidation anilides C H activation cobalt catalysis dioxazolones |
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