A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs |
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| Authors: | Dr. Georges Mouchaham Dr. Lucy Cooper Dr. Nathalie Guillou Dr. Charlotte Martineau Dr. Erik Elkaïm Dr. Sandrine Bourrelly Dr. Philip L. Llewellyn Dr. Clémence Allain Dr. Gilles Clavier Dr. Christian Serre Dr. Thomas Devic |
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| Affiliation: | 1. Institut Lavoisier, UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, Université Paris‐Saclay, 45 avenue des Etats‐Unis, 78035 Versailles (France);2. PPSM, CNRS UMR8531, Ecole Normale Supérieure de Cachan, Université Paris‐Saclay, 61 avenue du Président Wilson, 94235 Cachan (France);3. Synchrotron Soleil, beamline Cristal, L'Orme des Merisiers, Saint‐Aubin, 91192 Gif‐sur Yvette cedex (France);4. Aix‐Marseille Univ., CNRS, MADIREL UMR 7246, 13397 Marseille (France) |
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| Abstract: | A novel Zr‐chain based MOF, namely MIL‐163, was designed and successfully synthesized using a bis‐1,2,3‐trioxobenzene ligand. Endowed with large square‐shaped channels of 12 Å width, it shows remarkable water uptake (ca. 0.6 cm3 g?1 at saturating vapor pressure) and a remarkable stability in simulated physiological media, where archetypical Zr carboxylate MOFs readily degrade. |
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| Keywords: | chemical stability MOFs phenolate water adsorption zirconium |
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