A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs |
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| Authors: | Dr Georges Mouchaham Dr Lucy Cooper Dr Nathalie Guillou Dr Charlotte Martineau Dr Erik Elkaïm Dr Sandrine Bourrelly Dr Philip L Llewellyn Dr Clémence Allain Dr Gilles Clavier Dr Christian Serre Dr Thomas Devic |
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| Institution: | 1. Institut Lavoisier, UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, Université Paris‐Saclay, 45 avenue des Etats‐Unis, 78035 Versailles (France);2. PPSM, CNRS UMR8531, Ecole Normale Supérieure de Cachan, Université Paris‐Saclay, 61 avenue du Président Wilson, 94235 Cachan (France);3. Synchrotron Soleil, beamline Cristal, L'Orme des Merisiers, Saint‐Aubin, 91192 Gif‐sur Yvette cedex (France);4. Aix‐Marseille Univ., CNRS, MADIREL UMR 7246, 13397 Marseille (France) |
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| Abstract: | A novel Zr‐chain based MOF, namely MIL‐163, was designed and successfully synthesized using a bis‐1,2,3‐trioxobenzene ligand. Endowed with large square‐shaped channels of 12 Å width, it shows remarkable water uptake (ca. 0.6 cm3 g?1 at saturating vapor pressure) and a remarkable stability in simulated physiological media, where archetypical Zr carboxylate MOFs readily degrade. |
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| Keywords: | chemical stability MOFs phenolate water adsorption zirconium |
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