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Surface tension of concentrated cellulose solutions in 1-ethyl-3-methylimidazolium acetate |
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| Authors: | Jeremias Schuermann Tim Huber Deborah LeCorre Gérard Mortha Mathieu Sellier Benoît Duchemin Mark P Staiger |
| Institution: | 1.Department of Mechanical Engineering,University of Canterbury,Christchurch,New Zealand;2.Biomolecular Interaction Centre,University of Canterbury,Christchurch,New Zealand;3.LGP2, UMR 5518,Institut Polytechnique de Grenoble,Saint-Martin d’Hères,France;4.LOMC, UMR 6294,CNRS-Université du Havre,Le Havre,France |
| Abstract: | Four sources of cellulose with different molecular weights were dissolved in the ionic liquid 1-ethyl-3-methylimidazolium acetate at 100 °C over a 10 h period. The solution densities were determined and these results were subsequently utilised to access the influence of dissolved cellulose on surface tension properties of cellulose/ionic liquid solutions. Surface tension measurements revealed increasing molecular weight and concentration reduced surface tension while temperature increases showed the opposite effect. These results are consistent with that of repulsive polymer-wall interactions near the interface in good solvent conditions. The semi-flexible nature of this carbohydrate in solution can help explain deviations of these results when compared to ideal flexible chains. |
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