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| 新型多氮化合物1,1＇-偶氮-1,2,3-三唑的合成与性能研究 | |
| 引用本文： | 李玉川,李生华,祁才,张慧娟,朱梦宇,庞思平.新型多氮化合物1,1＇-偶氮-1,2,3-三唑的合成与性能研究[J].化学学报,2011,69(18):2159-2165. |
| 作者姓名： | 李玉川 李生华 祁才 张慧娟 朱梦宇 庞思平 |
| 作者单位： | 1. 北京理工大学材料学院,北京100081／北京理工大学生命学院,北京100081 2. 北京理工大学材料学院,北京,100081 3. 北京理工大学生命学院,北京,100081 |
| 基金项目： | 国家自然科学基金(No.20772011)资助项目 |
| 摘 要： | 以1-氨基-1,2,3-三唑（1）为原料,经二氯异氰尿酸钠（SDCI）氧化偶联合成了具有稳定N8结构（8个氮原子直接相连）和光致变色特性的新型多氮化合物1,1＇-偶氮-1,2,3-三唑（2）,通过IR,Raman,1H NMR,13C NMR,MS,元素分析等手段对其进行了表征;分离出了偶合反应副产物1H-1,2,3-... |
| 关 键 词： | 多氮化合物 1 2 3-三唑 氧化偶联 合成 性能 机理 理论计算 |
Synthesis and Performance of A Novel Poly-nitrogen Compound 1,1'-Azobis-1,2,3-triazole |
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| Li,Yuchuana,b Li,Shenghuaa Qi,Caia Zhang,HuijuanbZhu,Mengyu,b Pang,Siping,a.Synthesis and Performance of A Novel Poly-nitrogen Compound 1,1'-Azobis-1,2,3-triazole[J].Acta Chimica Sinica,2011,69(18):2159-2165. | |
| Authors: | Li Yuchuana b Li Shenghuaa Qi Caia Zhang HuijuanbZhu Mengyu b Pang Siping a |
| Institution: | Li,Yuchuana,b Li,Shenghuaa Qi,Caia Zhang,HuijuanbZhu,Mengyu*,b Pang,Siping,a(a School of Material Science and Engineering,Beijing Institute of Technology,Beijing 100081)(b School of Life Science and Technology,Beijing 100081) |
| Abstract: | 1,1'-Azobis-1,2,3-triazole(2),a novel poly-nirogen compound with stable N8 structure(eight directly linked nitrogen atoms) and photochromism,has been synthesized from 1-amino-1,2,3-triazole(1) by the oxidative coupling reaction(sodium dichloroisocyanurate(SDCI) as the oxidant) and its structure were characterized by IR,Raman,1H NMR,13C NMR,MS and elementary analysis techniques.1H-1,2,3-triazole(3) was separated as the by-product and the decomposed mechanism of 2 were presumed.The structure of 2 was also est... |
| Keywords: | poly-nitrogen compound 1 2 3-triazole oxidative coupling synthesis performance mecha-nism theoretical calculation |
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