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微乳液法制备Pt/ZrO2催化剂及其催化加氢活性研究
引用本文:宋华,汪淑影,李锋.微乳液法制备Pt/ZrO2催化剂及其催化加氢活性研究[J].化学通报,2011(10):947-951.
作者姓名:宋华  汪淑影  李锋
作者单位:东北石油大学化学化工学院;
摘    要:采用十六烷基三甲基溴化铵(CTAB)/正丁醇/环己烷/H2PtCl6微乳液体系,以N2H4.H2O为还原剂,ZrO2为载体,制备Pt/ZrO2催化剂。以对氯硝基苯(p-CNB)选择加氢反应为探针,考察微乳液组成及载体焙烧温度对Pt/ZrO2催化剂催化活性的影响。由TEM、XRD对载体和催化剂进行表征。结果表明,采用微乳...

关 键 词:微乳液  Pt/ZrO2  对氯硝基苯  选择加氢

Study on the Preparation of Pt/ZrO_2 Catalyst by Microemulsion and Its Catalytic Activity for Selective Hydrogenation
Song Hua,Wang Shuying,Li Feng.Study on the Preparation of Pt/ZrO_2 Catalyst by Microemulsion and Its Catalytic Activity for Selective Hydrogenation[J].Chemistry,2011(10):947-951.
Authors:Song Hua  Wang Shuying  Li Feng
Institution:Song Hua,Wang Shuying,Li Feng(College of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318)
Abstract:The Pt/ZrO2 catalyst was prepared by using hydrazine as reductant and ZrO2 as support in CTAB/n-butanol/cyclohexane/H2PtCl6 microemulsion.Effect of the composition of microemulsion and calcination temperature on the activity for selective hydrogenation over Pt/ZrO2 catalyst was studied using p-chloronitrobenzene(p-CNB) selective hydrogenation as a probe reaction.The support and catalyst were characterized by TEM and XRD.The results showed that the Pt/ZrO2 catalyst prepared using the microemulsion consisted ...
Keywords:Microemulsion  Pt/ZrO2  p-Chloronitrobenzene  Selective hydrogenation  
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