Schiff base complexes of dioxouranium(VI), III. Commun.: Dioxouranium(VI) complexes of bibasic tetradentateSchiff bases |
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Authors: | Ram G Vijay Jagdish P Tandon |
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Institution: | (1) Chemical Laboratories, University of Rajasthan, IND-302004 Jaipur. 4, India |
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Abstract: | Bibasic tetradentateSchiff bases having the donor system OH–NX–NX–OH have been shown to form UO2(NO3)2(SBH2) type of derivatives SBH2 is the molecule of the bibasic tetradentateSchiff bases such as HOC6H4C(R) N(CH2)
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N C(R)C6H4OH (where R=H or CH3 andn=2 or 3) and HOC(R ) CHC(CH3) N(CH2)
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N C(CH3)CH C(R )OH (where R =CH3 or C6H5 andn=2 or 3)]. The 1 1 stoichiometry of these complexes is shown by elemental analysis and conductometric titrations. The molar conductence values in nitrobenzene indicate the non-electrolytic behaviour and the magnetic susceptibility measurements by the Gouy method show these complexes to be diamagnetic.With 1 Figure |
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