Three-Body Photodissociation of Thionyl Chloride |
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| Authors: | Bumaliya Abulimiti Qiao-li Hao Chen Qin Mei Xiang Bing Zhang |
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| Affiliation: | a.College of Physics and Electronic Engineering, Xinjiang Normal University, Urumqi 830054, Chinab.State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, China |
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| Abstract: | The ultrafast photodissociation dynamics of thionyl chloride after excitation with a 235 nm pump pulse has been studied using a femtosecond time-resolved mass spectroscopy. The observed parent transient suggests that the excited states initiated by 235 nm are very shortlived, that is, approximately 166 fs. Not only a stepwise three-body dissociation pathway but also a concerted three-body dissociation pathway is observed. |
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| Keywords: | Photodissociation Thionyl chloride Three-body Time-resolved study |
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