| Synthesis,Crystal Structure and Electrochemical Property of a Dinuclear Manganese（Ⅱ） Complex [Mn_2（C_（12）H_8N_2）_4（C_8H_5O_4）_2]（C_8H_4O_4）·H_2O |
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| 引用本文： | 张少华,杨颖群,李薇,李昶红,匡云飞.Synthesis,Crystal Structure and Electrochemical Property of a Dinuclear Manganese（Ⅱ） Complex [Mn_2（C_（12）H_8N_2）_4（C_8H_5O_4）_2]（C_8H_4O_4）·H_2O[J].结构化学,2011,30(10):1497-1500. |
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| 作者姓名： | 张少华 杨颖群 李薇 李昶红 匡云飞 |
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| 作者单位： | Department of Chemistry and Materials Science;Hengyang Normal University;Hengyang;Department of Materials and Chemical Engineering;Hunan Institute of Technology; |
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| 基金项目： | Sponsored by the Scientific Research Fund of Hunan Provincial Education Department (B21018); the Construct Program of the Key Disciplines in Hunan Province |
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| 摘 要： | One dinuclear manganese(II)complex Mn2(C12H8N2)4(C8H5O4)2](C8H4O4)·H2O has been synthesized with o-phthalic acid and 1,10-phenanthroline.The crystal structure was determined by X-ray diffraction.The crystal belongs to the triclinic system,space group P1 with a = 1.17767(3),b = 1.22292(2),c = 1.35860(3)nm,α = 110.5300(10),β = 97.6140(10),γ = 93.7300(10)o,V = 1.80307(7)nm3,Dc = 1.404 g/cm3,Z = 2,F(000)= 784,the final GOOF = 1.047,R = 0.0398 and wR = 0.1038.The crystal structure of the title complex consists of one Mn2(C12H8N2)4(C8H5O4)2]2+ cation,one uncoordinate o-phthalate anion(C8H4O4)2-and one uncoordinate water molecule.In Mn2(C12H8N2)4(C8H5O4)2]2+,the central Mn(II)ion is coordinated by four nitrogen atoms and two oxygen atoms to give a distorted octahedral coordination geometry.The electrochemical property of the title complex was also studied.
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| 关 键 词： | 锰（Ⅱ）配合物 晶体结构测定 电化学性能 合成 双核 邻苯二甲酸 邻菲罗啉 射线衍射 |
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