| Synthesis and Crystal Structure of a Zinc（Ⅱ）Complex with 2,2＇-Diphenic Acid and Benzimidazole Ligands |
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| 引用本文： | 李秀梅,王庆伟,刘博.Synthesis and Crystal Structure of a Zinc（Ⅱ）Complex with 2,2＇-Diphenic Acid and Benzimidazole Ligands[J].结构化学,2011,30(10):1464-1468. |
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| 作者姓名： | 李秀梅 王庆伟 刘博 |
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| 作者单位： | Department of Chemistry;Tonghua Teachers College;College of Chemistry;Jilin Normal University; |
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| 基金项目： | Supported by the Science and Technology Research Projects of the Education Office of Jilin Province (No.2011.459) |
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| 摘 要： | A new complex Zn1.5(dpa)1.5(bim)]2n(dpa = 2,2-diphenic acid,bim = benzimida-zole)1 has been hydrothermally synthesized and structurally characterized by elemental analysis,IR,fluorescence spectrum and single-crystal X-ray diffraction.The complex crystallizes in monoclinic,space group C2/c with a = 18.773(8),b = 16.560(7),c = 16.417(9),β = 94.737(9)o,V = 5086(4)3,C56H36N4O12Zn3,Mr = 1153.00,Dc = 1.506 g/cm3,μ(MoKα)= 1.472 mm1,F(000)= 2344,Z = 4,the final R = 0.0573 and wR = 0.1164 for 2968 observed reflections(I > 2σ(I)).It exhibits a one-dimensional chain-like structure and shows luminescent property in the blue region.
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| 关 键 词： | 晶体结构 水热合成 联苯酸 咪唑类配体 配合物 一维链状结构 元素分析 红外光谱 |
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