| Synthesis,Structure,and Magnetic Property of One Snake-shaped Copper（Ⅱ）-organic Compound：Cu[Cu_2（PP）_2]（CBPC）_2]·2（H_2O） |
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| 引用本文： | 范黎明,李大成,魏培海,张修堂,窦建民.Synthesis,Structure,and Magnetic Property of One Snake-shaped Copper（Ⅱ）-organic Compound：Cu[Cu_2（PP）_2]（CBPC）_2]·2（H_2O）[J].结构化学,2011,30(10):1381-1386. |
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| 作者姓名： | 范黎明 李大成 魏培海 张修堂 窦建民 |
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| 作者单位： | Advanced Material Institute of Research;Department of Chemistry and Chemical Engineering;Qilu Normal University;College of Chemistry and Chemical Engineering;Liaocheng University; |
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| 基金项目： | supported by Financial support from the Natural Science Foundation of Shandong (BR2010BQ023) and Qilu Normal University |
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| 摘 要： | One novel copper(II)-organic compound,namely CuCu2(PP)2](CBPC)2]·2(H2O)(1,H2CBPC = 1-(2'-carboxybiphenyl-4-yl)methyl]-2-propylimidazole-4-carboxylic acid,HPP = 3-(2-pyridyl)pyrazole),was designed and synthesized under hydrothermal conditions.X-ray diffraction analysis reveals that two Cu(II)ions in the quasi-planar dimmer of Cu2(PP)2] are linked by the carboxylate oxygen atoms on the phenyl ring and the imidazole ring,respectively,yielding one snake-shaped structure.Magnetic measurements reveal that compound 1 shows the strongly antiferromagnetic property.Crystal data of 1:C58H52Cu3N10O10,Mr = 1239.72,monoclinic,P21/c,a = 14.900(7),b = 15.029(7),c = 12.308(6),β = 102.519(9)o,V = 2691(2)3,Z = 2,Dc = 1.530 g/cm3,F(000)= 1274,μ = 1.246 mm-1,R = 0.0416,wR = 0.0780(I > 2σ(I))and S = 0.999.
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| 关 键 词： | 有机化合物 HPP H2O 磁学性质 合成 结构 X射线衍射分析 铜 |
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