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| A New Series of Charge-assisted Hydrogen-bonded Host Frameworks Based on [Co（en）_3]~（3＋）and Dicarboxylates | |
| 引用本文： | 林志盛,Slavi C.Sevov,赵景泰.A New Series of Charge-assisted Hydrogen-bonded Host Frameworks Based on [Co（en）_3]~（3＋）and Dicarboxylates[J].结构化学,2011,30(10):1419-1427. |
| 作者姓名： | 林志盛 Slavi C.Sevov 赵景泰 |
| 作者单位： | Key Laboratory of Transparent Opto-functional Inorganic Materials of Chinese Academy of Sciences;Shanghai Institute of Ceramics;Department of Chemistry & Biochemistry;University of Notre Dame;Notre Dame;Graduate School of Chinese Academy of Sciences; |
| 基金项目： | Supported by the National Science Foundation (DMR-0600320) |
| 摘 要： | A new series of metal complex carboxylates(MCC)made of Co(en)3]3+(MC)and either 2,6-naphthalenedicarboxylic(NDC)or 4,4-biphenyldicarboxylic(BPDC)were synthesized and structurally characterized.The four new compounds have a general formula(MC)2(C)3·n(guest)with the guests of dimethylformamide(DMF)and dimethyl sulfoxide(DMSO)and water.All the structures represent a pillared-layer type,where the layer consists of MC cations,carboxylate anions or water molecules via a large number of hydrogen bonds.The layers are pillared by the organic residues of NDC or BPDC,resulting in the inclusion cavities where the guest molecules reside.Although their topological structures are similar,they crystallize in different crystal structures due to the rearrangement of pillars and hydrogen-bonded layers. |
| 关 键 词： | 羧酸酯 氢键 新系 框架 主机 充电 基础 二元 |
A New Series of Charge-assisted Hydrogen-bonded Host Frameworks Based on [Co(en)_3]~(3+)and Dicarboxylates |
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| LIN Zhi-Sheng , Slavi C. Sevov , ZHAO Jing-Tai.A New Series of Charge-assisted Hydrogen-bonded Host Frameworks Based on [Co(en)_3]~(3+)and Dicarboxylates[J].Chinese Journal of Structural Chemistry,2011,30(10):1419-1427. | |
| Authors: | LIN Zhi-Sheng Slavi C Sevov ZHAO Jing-Tai |
| Institution: | 1. Key Laboratory of Transparent Opto-functional Inorganic Materials of ChineseAcademy of Sciences, Shanghai Institute of Ceramics, Shanghai 200050, China／Department of Chemistry ＆ Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA／Graduate School of Chinese Academy of Sciences, Beijing 100039, China 2. Department of Chemistry ＆ Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA 3. Key Laboratory of Transparent Opto-functional Inorganic Materials of ChineseAcademy of Sciences, Shanghai Institute of Ceramics, Shanghai 200050, China |
| Abstract: | A new series of metal complex carboxylates(MCC)made of Co(en)3]3+(MC)and either 2,6-naphthalenedicarboxylic(NDC)or 4,4-biphenyldicarboxylic(BPDC)were synthesized and structurally characterized.The four new compounds have a general formula(MC)2(C)3·n(guest)with the guests of dimethylformamide(DMF)and dimethyl sulfoxide(DMSO)and water.All the structures represent a pillared-layer type,where the layer consists of MC cations,carboxylate anions or water molecules via a large number of hydrogen bonds.The layers are pillared by the organic residues of NDC or BPDC,resulting in the inclusion cavities where the guest molecules reside.Although their topological structures are similar,they crystallize in different crystal structures due to the rearrangement of pillars and hydrogen-bonded layers. |
| Keywords: | metal complex carboxylate host frameworks hydrogen bond crystal structure |
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