Natural product biosynthesis inspired concise and stereoselective synthesis of benzopyrones and related scaffolds |
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| Authors: | Baskar Baburaj Dakas Pierre-Yves Kumar Kamal |
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| Affiliation: | Max-Planck-Institut fu?r molekulare Physiologie, Otto-Hahn Strasse 11, 44227-Dortmund, Germany. |
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| Abstract: | A natural product biosynthesis-inspired strategy to explore biologically relevant chemical space is presented. A phosphine-catalyzed cascade and stereoselective annulation provides a common tricyclic benzopyrone intermediate that was efficiently transformed into diverse and related naturally occurring scaffolds. |
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