Radical steps in the reactions of organometallic compounds with 2-methyl-2-nitrosopropane: experimental evaluation of the validity of the nitroxyl method for investigations of homolytic reactions of organometallic compounds |
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| Authors: | D F Grishin V K Cherkasov V A Dodonov |
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| Institution: | (1) N. I. Lobachevsky Nizhnii Novgorod State University, 23 prosp. Gagarina, 603600 Nizhnii Novgorod, Russian Federation;(2) Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600 Nizhnii Novgorod, Russian Federation |
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| Abstract: | Radical adducts formed in the reactions of organometallic compounds of group II-V elements and of some organochromium and organoiron compounds with 2-methyl-2-nitrosopropane and phenyl(tert-butyl)nitrone were studied by ESR. Nitroso compounds and nitrones can be used as selective spin traps for investigations of homolytic reactions involving organometallic compounds.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 916–920, May, 1994. |
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| Keywords: | radicals spin traps organometallic compounds ESR |
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