Hydrogen bonding in 2-hydroxy((di)thio)benzoates. II. X-ray structures of tetraethylammonium salts期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Hydrogen bonding in 2-hydroxy((di)thio)benzoates. II. X-ray structures of tetraethylammonium salts

Authors:	Kurt Mereiter Werner Mikenda Erich Steinwender

Institution:	(1) Institut für Mineralogie, Kristallographie und Strukturchemie, Technische Universität Wien, Getreidemarkt 9, A-1060 Vienna, Austria;(2) Institut für Organische Chemie, Universität Wien, Währingerstrae 38, A-1090 Vienna, Austria

Abstract:	X-ray structural data are reported for tetraethylammonium-2-hydroxythiobenzoate (C₁₅H₂₅NO₂S; orthorhombic,Pna2₁(33);a=14.155(2)Å,b=7.651(1)Å,c=14.855(2)Å;Z=4;R=0.038, at 295 K) and for tetraethylammonium-2-hydroxydithiobenzoate (C₁₅H₂₅NOS₂; orthorhombic,Pna2₁(33);a=15.668(4)Å,b=8.729(2)Å,c=12.350(3)Å;Z=4;R=0.031, at 295 K). In both compounds the OH groups are engaged in intramolecular O-HS hydrogen bonds (OS=2.88 and 2.89 Å, respectively).

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