Group-12 vdW dimers in free-jet supersonic beams: The legacy of Eugeniusz Czuchaj
continues |
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Authors: | J Koperski |
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Institution: | (1) Smoluchowski Institute of Physics, ul. Reymonta 4, 30-059 Kraków, Poland |
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Abstract: | Laser induced excitation and dispersed fluorescence spectra of
group-12 metal homoatomic dimers (Zn2, Cd2, Hg2) recorded at a number of
ultraviolet transitions provided information about interatomic potentials
of the ground and lower-lying excited electron energy states of the dimers.
The experimental studies were associated with calculations performed by
Eugeniusz Czuchaj that were related to interatomic potentials as well as
dipole moments for transitions between the ground and the excited
states of the dimers. In experiments the dimers were produced in free-jet
supersonic beams and were excited in a vacuum chamber with dye-laser beams.
Isotopically resolved vibrational transitions in low-resolution excitation
spectra and high-resolution rotational profiles of several vibrational
components as well as Condon internal diffraction patterns in dispersed
fluorescence spectra were recorded. Complex analyses of the spectra yielded
information about the ground- and excited-state potential bond lengths,
well depths as well as shapes of the investigated potentials in limited
regions of internuclear separations. The determined potential energy curves
were compared with results of Czuchaj providing conclusions related to the
accuracy of calculations and/or experiments as well as giving the
experimentalist information about planning experimental studies of molecular
potentials of the group-12 dimers. |
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