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| 配位聚合物{[Zn(CF3COO)2(C5H5ON)]·H2O}n的合成、晶体结构及表征 | |
| 引用本文： | 马卫兴,高健,钱保华,许兴友,陆路德,杨绪杰,汪信,宋海斌. 配位聚合物{[Zn(CF3COO)2(C5H5ON)]·H2O}n的合成、晶体结构及表征[J]. 无机化学学报, 2005, 21(5): 749-752 |
| 作者姓名： | 马卫兴 高健 钱保华 许兴友 陆路德 杨绪杰 汪信 宋海斌 |
| 作者单位： | 1. 南京理工大学材料化学实验室,南京,210094;淮海工学院化学工程系,连云港,222005 2. 南京理工大学材料化学实验室,南京,210094 3. 南开大学化学学院,天津,300071 |
| 基金项目： | 国家自然科学基金资助项目(No.50373019)，江苏省自然科学基金资助项目(No.BK2003097)，江苏省高校自然科学研究计划资助项目 |
| 摘 要： | new coordination polymer {[Zn(CF3COO)2(C5H5ON)]·H2O}n was synthesized based on the reaction of zinc(Ⅱ) trifluoroacetate and 3-hydroxypyridine(C5H5ON) in methanol medium for the first time. The structure of the coordination polymer was confirmed by IR, 1H NMR, elemental analysis and thermal analysis. The crystal structure of the coordination polymer was also determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/m, and crystallographic data of the coordination polymer are: a= 0.863 1(4) nm, b=0.717 7(3) nm, c=1.116 4(5) nm, α=γ=90°, β=107.542(6)°, V=0.659 4(5) nm3; Dc=2.037 g·cm-3; Z=2; F(000)=400; μ=1.969 mm-1. Zinc(Ⅱ) atom lies at the center of an octahedron formed by the coordination of zinc atom and six O atoms which come from four different trifluoroacetate ions and two different 3-hydroxypyridine molecules where each trifluoroacetate ion and 3-hydroxypyridine are coordinated to two different zinc ions to form coordination polymer. CCDC: 253909. |
| 关 键 词： | Zn(Ⅱ)配合物； 配位聚合物； 谱学表征； 晶体结构 |
| 文章编号： | 1001-4861(2005)05-0749-04 |
| 收稿时间： | 2004-09-27 |
| 修稿时间： | 2004-09-27 |
Synthesis,Crystal Structure and Spectral Characterization of Coordination Polymer {[Zn(CF3COO)2(C5H5ON)]· H2O}n |
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| MA Wei-Xing,GAO Jian,QIAN Bao-Hu,XU Xing-You,LU Lu-De,YANG Xu-Jie,WANG Xin and SONG Hai-Bin. Synthesis,Crystal Structure and Spectral Characterization of Coordination Polymer {[Zn(CF3COO)2(C5H5ON)]· H2O}n[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(5): 749-752 | |
| Authors: | MA Wei-Xing GAO Jian QIAN Bao-Hu XU Xing-You LU Lu-De YANG Xu-Jie WANG Xin SONG Hai-Bin |
| Affiliation: | Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094;Dept. of Chemical Technology, Huaihai Institute of Technology, Lianyungang 222005,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094;Dept. of Chemical Technology, Huaihai Institute of Technology, Lianyungang 222005,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094;Dept. of Chemical Technology, Huaihai Institute of Technology, Lianyungang 222005,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094 and College of Chemistry, Nankai University, Tianjin 300071 |
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