Reactions of substituted 8-oxatricyclo[3.2.1.02,4]octan-6-ones and 9-oxatricyclo[3.3.1.02,4]nonan-6-ones with methylmagnesium bromide and lithium aluminum hydride |
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| Authors: | A. P. Molchanov V. V. Diev Chan Quang Tung R. R. Kostikov |
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| Affiliation: | 1.St. Petersburg State University,St. Petersburg,Russia |
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| Abstract: | Substituted 8-oxatricyclo[3.2.1.02,4]octan-6-one and 9-oxatricyclo[3.3.1.02,4]-nonan-6-one obtained by treating substituted cyclopropenes with carbonyl ylides in reactions with methylmagnesium bromide and lithium aluminum hydride were stereoselectively converted into the corresponding alcohols. |
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