Non-ideal kinetics in vinyl polymerization: Note on primary radical termination in benzoyl peroxide initiated polymerization of vinyl chloride in dichloroethane |
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| Authors: | Solution EF Okieimen |
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| Institution: | Department of Chemistry, University of Wales, Institute of Science and Technology, Cardiff CFI 3NU, Wales UK |
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| Abstract: | The kinetics of vinyl chloride polymerization initiated by benzoyl peroxide doubly labelled with 14C and 'H were studied in 1,2-dichloroethane solution at 60°. The importance of primary radical termination in the polymerization is examined by kinetic analysis and by analysis of polymers for combined initiator fragments. |
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