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A viscometric study of poly(methyl methacrylate) in 2-alkoxyethanols
Authors:O Quadrat  L Mrkvičková
Institution:Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06 Prague 6 Czechoslovakia
Abstract:θ-Conditions, the temperature coefficient of unperturbed dimensions of the macromolecules and the thermodynamic interaction parameters ψ and κ were determined for solutions of poly(methyl methacrylate) in 2-alkoxyethanols (methoxy, ethoxy and butoxy). The results for this series of solvents fit the data reported for other solvents and dln r02/dT = 2.6 × 10?3K?1. The dependence of parameters ψ and κ exhibited deviations from the theoretical dependence, mainly near the limiting value ψ = 0.5.
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