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Synthesis and some structural data of nylon 18
Authors:G. Cojazzi  A.M. Drusiani  A. Fichera  V. Malta  F. Pilati  R. Zannetti
Affiliation:1. Centro di Studio per la Fisica delle Macromolecole del C.N.R., via Selmi, 2 Bologna, Italy;2. Istituto Chimico “G. Ciamician” dell''Università, via Selmi, 2 Bologna, Italy;3. Istituto Chimico della Facoltà di Ingegneria dell''Università, viale Risorgimento, 2 Bologna Italy;4. Istituto di Chimica Generale ed Inorganica dell''Università, via Loredan, 4 Padova, Italy
Abstract:The new polyamide nylon 18 was synthesized, mainly to investigate whether a rather large number of methylene groups in the monomeric unit might change the chain packing in comparison with that of lower even nylons. By X-ray diffraction measurements on a mono-oriented fibre, the following crystallographic parameters were found: a = 4.76 A?; b = 9.52 A?; c = 46.9 A? (fibre axis); γ = 120°. A γ-type packing for the chains was found, similar to that shown by other polyamides of the series.
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