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Polystyrene-supported Palladium(II) Ethylenediamine Complex: A Recyclable Catalyst for the Syntheses of 2-Benzyl- imidazo[2,1-b][1,3]benzothiazoles by Sonogashira Reaction
作者姓名:BAKHERAD Mohammad  BAHRAMIAN Bahram  NASR-ISFAHANI Hossein  KEIVANLOO Ali  SANG Golnaz
作者单位:Department of Chemistry, School of Sciences, Shahrood University of Technology, Shahrood, Iran
摘    要:The polymer-supported palladium(II) ethylenediamine complex was used as a catalyst for the heterocyclization during Sonogashira reaction between a substituted phenyl iodide and 2-amino-3-(2-propynyl)-1,3-benzothiazolium bromide, which could readily be recovered from the reaction medium by a simple filtration, and reused without a significant loss in its activity.

关 键 词:Sonogashira  coupling    supported  catalyst    ethylenediamine    heterogeneous  catalyst    aryl  iodides    imidazobenzothiazole
收稿时间:2008-1-6
修稿时间:2008-7-7

Polystyrene-supported Palladium(Ⅱ) Ethylenediamine Complex:A Recyclable Catalyst for the Syntheses of 2-Benzyl-imidazo[2,1-b][1,3]benzothiazoles by Sonogashira Reaction
BAKHERAD Mohammad,BAHRAMIAN Bahram,NASR-ISFAHANI Hossein,KEIVANLOO Ali,SANG Golnaz.Polystyrene-supported Palladium(II) Ethylenediamine Complex: A Recyclable Catalyst for the Syntheses of 2-Benzyl- imidazo[2,1-b][1,3]benzothiazoles by Sonogashira Reaction[J].Chinese Journal of Chemistry,2009,27(2):353-358.
Authors:BAKHERAD Mohammad  BAHRAMIAN Bahram  NASR-ISFAHANI Hossein  KEIVANLOO Ali  SANG Golnaz
Institution:1. Tel./Fax: 982733335441;2. Department of Chemistry, School of Sciences, Shahrood University of Technology, Shahrood, Iran
Abstract:The polymer‐supported palladium(II) ethylenediamine complex was used as a catalyst for the heterocyclization during Sonogashira reaction between a substituted phenyl iodide and 2‐amino‐3‐(2‐propynyl)‐1,3‐benzothiazolium bromide, which could readily be recovered from the reaction medium by a simple filtration, and reused without a significant loss in its activity.
Keywords:Sonogashira coupling  supported catalyst  ethylenediamine  heterogeneous catalyst  aryl iodides  imidazobenzothiazole
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