Arylation of geminally activated nitroethenes |
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Authors: | R I Baichurin N I Aboskalova E V Trukhin V M Berestovitskaya |
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Institution: | 1. Herzen State Pedagogical University of Russia, nab. r. Moiki 48, St. Petersburg, 191186, Russia
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Abstract: | 3-Aryl-2-nitroprop-2-enenitriles and 1,3-diphenyl-2-nitroprop-2-en-1-one reacted with N,N-dimethylaniline to give the corresponding arylation products, 3-aryl-3-(4-dimethylaminophenyl)-2-nitropropanenitriles and 3-(4-dimethylaminophenyl)-1,3-diphenyl-2-nitropropan-1-one, whose structure was confirmed by IR and 1H and 13C-{1H} spectroscopy with the use of 1H-13C HMQC and HMBC heteronuclear correlation techniques. |
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